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Chemistry, Inorganic Chemistry
Year 4

Ligands in organometallic chemistry


2. The following table lists infrared (IR) carbonyl stretching frequencies for three organometallic complexes.  Explain why the infrared frequencies increase as one proceeds down the series.
[V(CO)6] - 1860 cm-1
[Cr(CO)6] 2000 cm-1
[Mn(CO)6]+ 2090 cm-1

By OTA:  Hua Wei, PhD (IP)

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Working with half lives to determine the time required to reach a certain percentage of its initial concentration. - A first order reaction has a half-life of 157 seconds. How much time is required for the reactant to be reduced to 12.5% of its initial concentration?
Identifying ligands and their charges. - Identify the ligands and their charges in Co(en)2(CN)2+.
Determining the number of unpaired electrons in a complex ion. - Determine the number of unpaired electrons in an octahedral, high-spin iron(III) complex ion.
Determining the number of unpaired electrons in a strong-field complex ion. - Determine the number of unpaired electrons in an octahedral, strong-field Co(exponent positive 2) complex ion.
Calculating the maximum absorbance of light given a crystal field splitting energy. - The crystal field splitting energy for TiF6^-3 is 203 kJ/mol. At what wavelength does the maximum absorbance of light occur for this complex?

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