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Chemistry, Inorganic Chemistry
Year 4

Bonding in coordination chemistry


[Co(h20)6]3+ will oxidize water
[Co(Nh36]3+ is stable in aqueous solution

How is this possible? Both are mondentate ligands. I thought the proximity of the nitrogens after one has bonded to the cobalt would make it more likely to react, because the entropy would be lowered.They are also both low spin complexes

By OTA:  Hua Wei, PhD (IP)

OTA Rating:  4.2/5

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Bonding in coordination chemistry - Why do square planar geometries occur in d7, d8, and d9 ions with strong field- pi acceptor ligands, except in cases in which ligand geometry requires it?
Working with half lives to determine the time required to reach a certain percentage of its initial concentration. - A first order reaction has a half-life of 157 seconds. How much time is required for the reactant to be reduced to 12.5% of its initial concentration?
Identifying ligands and their charges. - Identify the ligands and their charges in Co(en)2(CN)2+.
Determining the number of unpaired electrons in a complex ion. - Determine the number of unpaired electrons in an octahedral, high-spin iron(III) complex ion.
Determining the number of unpaired electrons in a strong-field complex ion. - Determine the number of unpaired electrons in an octahedral, strong-field Co(exponent positive 2) complex ion.

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